Contamination in the rare-earth element orthophosphate reference samples

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Contamination in the Rare-Earth Element Orthophosphate Reference Samples

Several of the fourteen rare-earth element (plus Sc and Y) orthophosphate standards grown at Oak Ridge National Laboratory in the 1980s and widely distributed by the Smithsonian Institution's Department of Mineral Sciences, are significantly contaminated by Pb. The origin of this impurity is the Pb2P2O7 flux that is derived from the thermal decomposition of PbHPO4. The lead pyrophosphate flux i...

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A Re-examination of the Rare-earth-element Orthophosphate Standards in Use for Electron-microprobe Analysis

A re-examination of fourteen standards consisting of orthophosphates of the rare-earth elements, Sc and Y, grown at Oak Ridge National Laboratory in the 1980s and widely distributed by the Smithsonian Institution’s Department of Mineral Sciences, reveals that some of the material is significantly contaminated by Pb. The origin of this impurity is the Pb2P2O7 flux that is derived from the therma...

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...................................................................................................................... iii LIST OF TABLES ............................................................................................................ vii LIST OF FIGURES ......................................................................................................... viii ACKNOWLEDGMENTS ......

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ژورنال

عنوان ژورنال: Journal of Research of the National Institute of Standards and Technology

سال: 2002

ISSN: 1044-677X

DOI: 10.6028/jres.107.056